FISHER SCIENTIFIC, CHEMICAL DIV. -- ACETIC ACID,GLACIAL,838 -- 6810-00-221-1415
===================== Product Identification ===================== Product ID:ACETIC ACID,GLACIAL,838 MSDS Date:04/21/1992 FSC:6810 NIIN:00-221-1415 MSDS Number: BMDNK === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 OR 201-796-7523 Emergency Phone Num:201-796-7100 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (SARA III) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 99.8%MIN Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 3310 MG/KG. (SIGMA) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CORROSIVE. ACUTE- INHALATION MAY CAUSE PULMONARY EDEMA, SHORTNESS OF BREATH, HYPOTENSION. CONTACT WITH EYES CAN CAUSE SEVERE BURNS & CONJUNCTIVITIS. SKIN CONTACT CAN CAUSE SEVERE BURNS. READILY ABSORB S THROUGH SKIN. INGESTION MAY CAUSE HEMATURIA, CONVULSION, SHOCK & DEATH. CHRONIC- DERMATITIS, EROSION OF TEETH. Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN, MUTAGEN, TERATOGEN OR NEUROTOXIN. Effects of Overexposure:SEVERE IRRITATION OF RESPIRATORY TRACT, COUGHING, SEVERE IRRITATION AND PAIN OF EYES AND SKIN, SEVERE IRRITATION OF DIGESTIVE TRACT, NAUSEA, VOMITING, ABDOMINAL SPASMS, THIRST, DIFFICULTY IN SWALLOWIN G, RAPID AND WEAK PULSE, SLOW AND SHALLOW BREATHING, PNEUMONIA, CARDIOVASCULAR COLLAPSE, HEMOLYSIS, ALBUMINURIA. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL CARE IN ALL CASES. EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. KEEP EYELIDS OPEN. INHALATION:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. INGESTION:DO NOT USE GAS TRIC LAVAGE OR EMESIS. IF CONSCIOUS, IMMEDIATELY DRINK LARGE AMOUNT OF MILK/WATER. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=39.4C, 103.F Autoignition Temp:=463.9C, 867.F Lower Limits:4.0% @ 59C Upper Limits:16 % @ 92C Extinguishing Media:WATER SPRAY, CO2, ALCOHOL FOAM/DRY CHEMICAL. WATER MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:CARBON DIOXIDE AND PROBABLY CARBON MONOXIDE ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. WEAR PROPER PROTECTIVE EQUIPMENT. VENTILATE AREA. DO NOT RELEASE INTO SOIL, SEWER, STREAM. STOP LEAK IF POSSIBLE. NEUTRALIZE WITH SODA ASH OR LIME. WITH CLEAN SHOVEL , PLACE MATERIAL INTO CLEAN CONTAINER FOR DISPOSAL Neutralizing Agent:SODA ASH, LIME, SODIUM BICARBONATE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS AWAY FROM HEAT & FLAMES. Other Precautions:DANGER! CORROSIVE. DO NOT GET IN EYES, ON SKIN, ON CLOTHING.AVOID BREATHING VAPORS OR GAS. USE WITH ADEQUATE VENTILATION. PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. TREAT EMPTY CONTAINERS AS IF THEY WERE FULL DUE TO RESIDUES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH (NIOSH) APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE WHEN PERMISSIBLE EXPOSURE LIMITS ARE EXCEEDED. Ventilation:PROVIDE GENERAL VENTILATION OR LOCAL EXHAUST TO MEET OSHA PERMISSIBLE EXPOSURE LIMITS (OSHA PEL). Protective Gloves:NITRILE, NEOPRENE, VINYL, RUBBER Eye Protection:CHEMICAL SAFETY GOGGLES & FACE SHIELD Other Protective Equipment:USE RUBBER SPLASH APRON AND RUBBER BOOTS. EYEWASH AND SAFETY SHOWER SHOULD BE LOCATED NEARBY. DO NOT WEAR CONTACT LENSES Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F6 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=117.8C, 244.F Melt/Freeze Pt:=16.7C, 62.F Vapor Pres:11.8 @ 20C Vapor Density:2.7 Spec Gravity:1.0492 pH:2.4 Viscosity:1.22 CPS @20C Evaporation Rate & Reference:0.97 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID - STRONG PUNGENT, CHARACTERISTIC VINEGAR ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHROMIC ACID, SODIUM PEROXIDE, NITRIC ACID OR OTHER OXIDIZING MATERIALS, MOST METALS, ALKALIES, ACETALDEHYDE, PERCHLORIC Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURE. Hazardous Decomposition Products:CARBON DIOXIDE AND PROBABLY CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT FEDERAL, COUNTY, AND LOCAL ENVIRONMENTAL REGULATORS FOR GUIDANCE REGARDING PROPER DISPOSAL. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.